AAC is MP3's better-trained successor: cleaner sound from the same number of bits. It was born in 1997, an MPEG all-star team: Fraunhofer, Dolby, Sony, AT&T and Nokia, and its real weak spot is older or stubborn hardware that only ever learned MP3.
WMV is a time capsule from the Windows XP years: tidy little files with dated manners. Windows Media Video, usually inside an ASF container; once the backbone of DRM movie rentals. That makes it the right destination when what you need is old Windows archives and PowerPoint decks that still insist on it.