MP3 is the format that taught music to travel: small, scrappy, and welcome absolutely everywhere. It was born in 1993, Fraunhofer Institute, Germany, and its real weak spot is holding fine detail at low bitrates: it stays small by quietly discarding sound.
FLV is a relic of the Flash era: the format YouTube grew up on, stranded when Flash died. The Flash Video container, typically holding old H.263, VP6 or early H.264 streams. That makes it the right destination when what you need is nothing new: today it's mostly old downloads waiting to be rescued.