WEBM is video the way browsers like it: open, royalty-free and built to stream. It was born in 2010, Google, out of its VP8 acquisition, and its real weak spot is life outside the browser: editors, TVs and Apple devices get picky.
WMA is Windows' old house band: big in the early 2000s, mostly retired now. Windows Media Audio, in several variants including a rarely-sighted lossless one. That makes it the right destination when what you need is keeping aging Windows Media software and old archives happy.