FLV is a relic of the Flash era: the format YouTube grew up on, stranded when Flash died. It was born in 2002, Macromedia (later Adobe), for Flash Player, and its real weak spot is playing anywhere at all since Flash was switched off in 2020.
WMV is a time capsule from the Windows XP years: tidy little files with dated manners. Windows Media Video, usually inside an ASF container; once the backbone of DRM movie rentals. That makes it the right destination when what you need is old Windows archives and PowerPoint decks that still insist on it.